Assessment of Corrosion Resistance and Metal Ion Leaching of Nitinol Alloys

Nitinol usage for biomedical implant devices has received significant attention due to its high corrosion resistance and biocompatibility. However, surface treatments are known to affect surface charge, surface chemistry, morphology, wettability, and corrosion resistance. In this investigation, the corrosion resistance of a binary and various ternary Nitinol alloys was determined after being subjected to electropolishing, magnetoelectropolishing, and water boiling and passivation. Cyclic polarization in vitro corrosion tests were conducted in Phosphate Buffer Saline (PBS) in compliance with ASTM F 2129-08 before and after surface treatments. The concentrations of dissolved metal ions in the electrolyte were also determined by ICPMS.     

Incorporation of postconsumer polyurethane foam into a polymer/clay aerogel matrix

The feasibility of incorporating ground recycled polyurethane (PU) foam into clay/polymer aerogels was demonstrated, and a range of compositions were prepared and characterized to determine the effect of variation in the formulations on density and mechanical properties of the resulting materials. This study followed a modified combinatorial approach. Initially, experiments were performed in water using either sodium exchanged montmorillonite or laponite clay, poly(vinyl alcohol) (PVOH) solution as the polymer binder, and the recycled PU foam. Freezing and freeze‐drying the aqueous gels produced aerogels, which were characterized through density and mechanical testing, scanning electron microscopy, and thermal gravimetric analysis. The study was expanded by exploring alternative binder chemistries, including the use of an alginate polymer in place of the PVOH or adding a polyisocyanate as a crosslinking agent for PVOH. The effect of recycled PU foam content, clay type and level, and binder type and level on the mechanical properties of the aerogels were determined and will be discussed herein. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42586.     

Research Advancement in High-Performance Polyamides and Polyamide Blends Loaded with Layered Silicate

Polyamide comprises one of the major classes of polymers. Layered silicates (nanofiller) may enhance properties of polyamide-based hybrids even at very low content. Aliphatic polyamides (nylons) have often been chosen for commercial applications because of excellent physical and chemical properties. Aromatic polyamides (aramids) and aliphatic-aromatic polyamides have been predominantly useful as high-performance materials due to stiffness, low density, and low cost. Recently polyamide blends have become an important route to high-performance materials. Binary blends of polyamide/polypropylene, polyamide/polystyrene, polyamide/polymethyl methacrylate, polyamide/polyurethane, and others have been reported for nanocomposite formation with organoclay. However, ternary blend nanocomposite with nanoclays (PA6/mSEBS, PA6/EPDM-g-MA/H-HDPE) is rarely explored.     

Synthesis,Characterization and Catalytic Activities of Palladium(II) Nitroaryl Complexes

Two palladium(II) nitroaryl complexes trans-[bromo(p-nitrophenyl)bis(triphenylphosphine)palladium(II)] 1 and trans-[bromo(2,4-dinitrophenyl)bis(triphenylphosphine)palladium(II)] 2 have been synthesized. The complexes were characterized by FTIR and NMR (¹H, ¹³C and ³¹P) spectroscopy and elemental analysis. The molecular structure of complex 2, as confirmed by X-ray crystallography, reveals that the Pd atom and its neighboring groups (two PPh₃, Br and phenylene group) lie in a slightly distorted square plane. In the UV–Vis spectra of the complexes 1 and 2, the palladium to aryl charge transfer bands were observed. The emission peaks from the singlet excited states (S₁ → S₀) were observed in the photoluminescence spectra of the complexes. The thermal stability of the complexes has been studied by thermal gravimetric analysis (TGA). TGA data showed that both complexes are thermally stable up to 200 °C, and complex 1 is more stable than 2. The catalytic efficiency of the new palladium(II) complexes was studied as demonstrated using the Sonogashira coupling reactions with good yields. The experimental results suggest that the Sonogashira coupling reactions can be performed at moderate temperature (50 °C) using these new palladium(II) complexes as catalysts.     

Neutron radiation effects on metal oxide semiconductor (MOS) devices

The main purpose of this study is to provide the knowledge and data on Deuterium-Tritium (D-T) fusion neutron induced damage in MOS devices. Silicon metal oxide semiconductor (MOS) devices are currently the cornerstone of the modern microelectronics industry. However, when a MOS device is exposed to a flux of energetic radiation or particles, the resulting effects from this radiation can cause several degradation of the device performance and of its operating life. The part of MOS structure (metal oxide semiconductor) most sensitive to neutron radiation is the oxide insulating layer (SiO₂). When ionizing radiation passes through the oxide, the energy deposited creates electron-hole pairs. These electron-hole pairs have been seriously hazardous to the performance of these electronic components. The degradation of the current gain of the dual n-channel depletion mode MOS caused by neutron displacement defects, was measured using in situ method during neutron irradiation. The average degradation of the gain of the current is about 35 mA, and the change in channel current gain increased proportionally with neutron fluence. The total fusion neutron displacement damage was found to be 4.8 × 10⁻²¹ dpa per n/cm², while the average fraction of damage in the crystal of silicon was found to be 1.24 × 10⁻¹². All the MOS devices tested were found to be controllable after neutron irradiation and no permanent damage was caused by neutron fluence irradiation below 10¹⁰n/cm². The calculation results shows that (n,α) reaction induced soft-error cross-section about 8.7 × 10⁻¹⁴ cm², and for recoil atoms about 2.9 × 10⁻¹⁵ cm², respectively.     

Tooling device design for vibration-assisted high speed shaping of PMMA

PMMA optical components that are used as one of the most important parts of high precision equipments and machines are increasingly replacing the glass due to the various advantages of PMMA. Especially in Light Guide Panels, the PMMA sheet that is used in Liquid Crystal Displays plays an important role in scattering the incident light and requires very fine machining as the sheet is directly related to the optical characteristics of the panels. The High Speed End milling and High Speed Shaping processes that are widely adopted and applied to the precise machining of Light Incident Plane still have quality problems, such as cracks, breakages, poor waviness, and straightness. This paper presents the tooling device design for machining a Light Incident Plane through vibration-assisted High Speed Shaping for increasing the optical quality by minimizing the above-mentioned problems. The cutting tool and the tool post presented in this paper are designed by the authors to increase the magnitude of the cutting stroke by adopting the resonant frequency without weakening the stiffness and to reduce vibrations during even high speed feeding. The dynamic characteristics of the cutting tool and the tool post are evaluated through simulation and experiment as well. The results reveal very appropriate dynamic characteristics for vibration-assisted High Speed Shaping.     

Four-wave mixing reduction technique based on smart filter approach

This paper proposed a new technique to suppress the four-wave mixing (FWM) effect by using a smart filter technique. The behaviour of FWM and the performance of wavelength division multiplexing systems with 4 and 16 channels were simulated in the presence of the proposed technique. The simulation was also performed under different parameters such as input power, number of channels and channel spacing. The FWM power drastically decreases by 12 and 19 dB for the 4 and 16 channels, respectively, when the smart filter is used as compared with the conventional system. In terms of system performance, the suggested approach for 4 and 16 channels at the first channel offers low bit error rate (BER) values of 3.23 × 10^?23 and 1.7 × 10^?21, respectively. The smart filter with the channel spacing variation for the 4-channel system subsequently improved the BER value at the fourth channel. Results confirm that the smart filter approach is an active solution that can suppress the FWM effect in optical transmission systems.     

An overview of state of the art and research in the fields of sensible, latent and thermo-chemical thermal energy storage

Due to the increase in volatile renewable power and heat generation (wind or solar), thermal energy storage (TES) has obtained growing importance and interest. The technology can be distinguished into three main types: sensible, latent and thermochemical storage. Apart from low and medium temperature heat applications, high temperature TES also is an attractive means to store power in the form of heat (before the thermodynamic transformation process). Thermochemical storage allows for long duration seasonal storage of energy.